Tung, P.; Schuhmacher, A.; Schilling, P.; Bode, J. W.; Mankad, N. P. Preparation of Potassium Acyltrifluoroborates (KATs) from Carboxylic Acids by Copper-Catalyzed Borylation of Mixed Anhydrides. Angewandte Chemie, International Edition, 2022, 61, e202114513. https://doi.org/10.1002/anie.202114513 (First appeared as preprint on ChemRxiv, https://doi.org/10.33774/chemrxiv-2021-jt414)
Cheng, L.-J.; Zhao, S.; Mankad, N. P. One-Step Synthesis of Acylboron Compounds via Cu-Catalyzed Carbonylative Borylation of Alkyl Halides. Angewandte Chemie, International Edition, 2021, 60, 2094-2098. https://doi.org/10.1002/anie.202012373.
(First appeared as preprint on ChemRxiv, https://doi.org/10.26434/chemrxiv.12818180.v1 )
*ACIE Hot Paper*
Cheng, L.-J.; Mankad, N. P. Cu-Catalyzed Carbonylative Silylation of Alkyl Halides: Efficient Access to Acylsilanes. Journal of the American Chemical Society2020, 142, 80-84. https://doi.org/10.1021/jacs.9b12043
* Highlight in Synfacts by M. Lautens & R. Ross
* Entry in Organic Chemistry Portal
Zhao, S.; Mankad, N. P. Synergistic Copper-Catalyzed Reductive Aminocarbonylation of Alkyl Iodides with Nitroarenes. Organic Letters2019, 21, 10106-10110. https://doi.org/10.1021/acs.orglett.9b04092
* Entry in Organic Chemistry Portal
Zhao, S.; Mankad, N. P. Metal-Catalysed Radical Carbonylation Reactions. Catalysis Science & Technology2019, 9, 3603-3613. https://doi.org/10.1039/C9CY00938H
*Mini-review*
Cheng, L.-J.; Mankad, N. P. Copper‐Catalyzed Borocarbonylative Coupling of Internal Alkynes with Unactivated Alkyl Halides: Modular Synthesis of Tetrasubstituted β‐Borylenones. Angewandte Chemie, International Edition2018, 57, 10328-10332. https://doi.org/10.1002/anie.201804883
Zhao, S.; Mankad, N. P. Cu-catalyzed Hydroxymethylation of Unactivated Alkyl Iodides with CO to Provide One Carbon Extended Alcohols. Angewandte Chemie, International Edition2018, 57, 10328-10332. https://doi.org/10.1002/anie.201801814
Cheng, L.-J.; Islam, S. M.; Mankad, N. P. Synthesis of Allylic Alcohols via Cu-Catalyzed Hydrocarbonylative Coupling of Alkynes with Alkyl Halides. Journal of the American Chemical Society2018, 140, 1159-1164. https://doi.org/10.1021/jacs.7b12582
Cheng, L.-J.; Mankad, N. P. Cu-Catalyzed Hydrocarbonylative C-C Coupling of Terminal Alkynes with Alkyl Iodides. Journal of the American Chemical Society2017, 139, 10200-10203. https://doi.org/10.1021/jacs.7b05205
* Entry in Organic Chemistry Portal
Pye. D. R.; Cheng. L.-J.; Mankad, N. P. Cu/Mn Bimetallic Catalysis Enables Carbonylative Suzuki-Miyaura Coupling with Unactivated Alkyl Electrophiles. Chemical Science2017, 8, 4750-4755. https://doi.org/10.1039/C7SC01170A
* Cover article
Mankad Group
-- We can do with two metals
what you can do with one --