Publications:
Multicomponent Carbonylative C-C and C-X Coupling Reactions

  1. Tung, P.; Mankad, N. P. Photochemical Synthesis of Acyl Fluorides Using Copper-Catalyzed Fluorocarbonylation of Alkyl Iodides. Organic Letters 2024ASAPhttps://doi.org/10.1021/acs.orglett.4c00967 (First appeared as preprint on ChemRxiv, https://doi.org/10.26434/chemrxiv-2023-fjtf1)
  2. Tung, P.; Mankad, N. P. Light-Mediated Synthesis of Aliphatic Anhydrides by Cu-Catalyzed Carbonylation of Alkyl Halides. Journal of the American Chemical Society 2023, 145, 9423-9427. https://doi.org/10.1021/jacs.3c01224 (First appeared as a preprint on ChemRxiv, https://doi.org/10.26434/chemrxiv-2022-gthrk-v2)
    *Entry in Organic Chemistry Portal
  3. Tung, P.; Schuhmacher, A.; Schilling, P.; Bode, J. W.; Mankad, N. P. Preparation of Potassium Acyltrifluoroborates (KATs) from Carboxylic Acids by Copper-Catalyzed Borylation of Mixed Anhydrides. Angewandte Chemie, International Edition, 2022, 61, e202114513. https://doi.org/10.1002/anie.202114513 (First appeared as preprint on ChemRxiv, https://doi.org/10.33774/chemrxiv-2021-jt414)
  4. Cheng, L.-J.; Mankad, N. P.Copper-Catalyzed Carbonylative Coupling of Alkyl Halides. Accounts of Chemical Research 2021, 54, 2261-2274. https://doi.org/10.1021/acs.accounts.1c00115
  5. Cheng, L.-J.; Zhao, S.; Mankad, N. P. One-Step Synthesis of Acylboron Compounds via Cu-Catalyzed Carbonylative Borylation of Alkyl Halides. Angewandte Chemie, International Edition, 202160, 2094-2098. https://doi.org/10.1002/anie.202012373.
    (First appeared as preprint on ChemRxiv, https://doi.org/10.26434/chemrxiv.12818180.v1 )
    *ACIE Hot Paper*
  6. Cheng, L.-J.; Mankad, N. P. C–C and C–X coupling reactions of unactivated alkyl electrophiles using copper catalysis. Chemical Society Reviews 2020, 49, 8036-8064.. https://doi.org/10.1039/D0CS00316F
    Special Themed Issue: 2020 Emerging Investigators
    *Special themed issue: Earth Abundant Metals in Catalysis
  7. Cheng, L.-J.; Mankad, N. P. Cu-Catalyzed Carbonylative Silylation of Alkyl Halides: Efficient Access to Acylsilanes.  Journal of the American Chemical Society 2020142, 80-84. https://doi.org/10.1021/jacs.9b12043
    * Highlight in Synfacts by M. Lautens & R. Ross
    * Entry in Organic Chemistry Portal
  8. Zhao, S.; Mankad, N. P. Synergistic Copper-Catalyzed Reductive Aminocarbonylation of Alkyl Iodides with Nitroarenes.  Organic Letters 201921, 10106-10110. https://doi.org/10.1021/acs.orglett.9b04092
    * Entry in Organic Chemistry Portal
  9. Zhao, S.; Mankad, N. P. Metal-Catalysed Radical Carbonylation Reactions.  Catalysis Science & Technology 20199, 3603-3613. https://doi.org/10.1039/C9CY00938H
    *Mini-review*
  10. Cheng, L.-J.; Mankad, N. P.  Copper‐Catalyzed Borocarbonylative Coupling of Internal Alkynes with Unactivated Alkyl Halides: Modular Synthesis of Tetrasubstituted β‐Borylenones.  Angewandte Chemie, International Edition 201857, 10328-10332. https://doi.org/10.1002/anie.201804883
  11. Zhao, S.; Mankad, N. P.  Cu-catalyzed Hydroxymethylation of Unactivated Alkyl Iodides with CO to Provide One Carbon Extended Alcohols.  Angewandte Chemie, International Edition 201857, 10328-10332. https://doi.org/10.1002/anie.201801814
  12. Cheng, L.-J.; Islam, S. M.; Mankad, N. P. Synthesis of Allylic Alcohols via Cu-Catalyzed Hydrocarbonylative Coupling of Alkynes with Alkyl Halides.  Journal of the American Chemical Society 2018140, 1159-1164. https://doi.org/10.1021/jacs.7b12582
  13. Cheng, L.-J.; Mankad, N. P. Cu-Catalyzed Hydrocarbonylative C-C Coupling of Terminal Alkynes with Alkyl Iodides.  Journal of the American Chemical Society 2017139, 10200-10203. https://doi.org/10.1021/jacs.7b05205
    * Entry in Organic Chemistry Portal
  14. Pye. D. R.; Cheng. L.-J.; Mankad, N. P. Cu/Mn Bimetallic Catalysis Enables Carbonylative Suzuki-Miyaura Coupling with Unactivated Alkyl Electrophiles.  Chemical Science 20178, 4750-4755. https://doi.org/10.1039/C7SC01170A
    * Cover article

Department of Chemistry
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